PDF (15199K)
摘要
2∶17型SmCo基永磁材料因其优异的内禀磁性能、独特的纳米胞状结构及元素梯度分布特征,展现出极高的矫顽力和稳定的剩磁温度特性,在航空航天、精密仪器及国防工业等领域具有重要应用价值。近年来,随着相关领域技术升级,对磁体的温度稳定性和综合性能提出了更高要求。系统综述了该材料在高磁能积、低温度系数及高温服役性能方面的研究进展,重点分析了时效处理过程中微结构演变规律与变温矫顽力机制,并对未来发展方向进行了展望。
Abstract
2∶17-type SmCo permanent magnets, characterized by their excellent intrinsic magnetic properties, unique nano-cellular structure, and element gradient distribution, exhibit remarkably high coercivity and stable remanence temperature characteristics, and hold significant application value in aerospace, precision instruments, and defense industries. In recent years, with the technological upgrades in related fields, higher demands have been placed on the temperature stability and overall performance of magnets. This review systematically summarizes the research progress of the material in terms of high magnetic energy product, low temperature coefficient, and high-temperature service performance, with a focus on analyzing the microstructural evolution during aging treatment and the temperature-dependent coercivity mechanism. Future development directions are also discussed.
关键词
Key words
[Author(id=1291794370388021965, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=longzan@emails.bjut.edu.cn, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1291794370450936527, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, authorId=1291794370388021965, language=EN, stringName=Zan LONG, firstName=Zan, middleName=null, lastName=LONG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1 College of Materials Science and Engineering, Beijing University of Technology , Beijing 100124, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1291794370501268177, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, authorId=1291794370388021965, language=CN, stringName=陇赞, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1 北京工业大学 材料科学与工程学院 , 北京 100124, bio={"content":"陇赞(1996—), 男, 博士研究生, 主要从事永磁材料方面的研究, E-mail: longzan@emails.bjut.edu.cn
"}, bioImg=null, bioContent=陇赞(1996—), 男, 博士研究生, 主要从事永磁材料方面的研究, E-mail: longzan@emails.bjut.edu.cn
, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1291794370228638402, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, xref=1, ext=[AuthorCompanyExt(id=1291794370245415620, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, companyId=1291794370228638402, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1 College of Materials Science and Engineering, Beijing University of Technology , Beijing 100124, China), AuthorCompanyExt(id=1291794370262192838, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, companyId=1291794370228638402, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1 北京工业大学 材料科学与工程学院 , 北京 100124)])]), Author(id=1291794370551599828, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, orderNo=1, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1291794370618708694, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, authorId=1291794370551599828, language=EN, stringName=Dongtao ZHANG, firstName=Dongtao, middleName=null, lastName=ZHANG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1 College of Materials Science and Engineering, Beijing University of Technology , Beijing 100124, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1291794370673234648, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, authorId=1291794370551599828, language=CN, stringName=张东涛, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1 北京工业大学 材料科学与工程学院 , 北京 100124, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1291794370228638402, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, xref=1, ext=[AuthorCompanyExt(id=1291794370245415620, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, companyId=1291794370228638402, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1 College of Materials Science and Engineering, Beijing University of Technology , Beijing 100124, China), AuthorCompanyExt(id=1291794370262192838, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, companyId=1291794370228638402, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1 北京工业大学 材料科学与工程学院 , 北京 100124)])]), Author(id=1291794370719371994, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, orderNo=2, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1291794370782286558, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, authorId=1291794370719371994, language=EN, stringName=Chaoyue ZHANG, firstName=Chaoyue, middleName=null, lastName=ZHANG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=2, address=2 Hangzhou Kede Magnetic Components Co., Ltd. , Hangzhou 311500, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1291794370832618208, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, authorId=1291794370719371994, language=CN, stringName=张超越, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=2, address=2 杭州科德磁业有限公司 , 杭州 311500, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1291794370312524488, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, xref=2, ext=[AuthorCompanyExt(id=1291794370325107401, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, companyId=1291794370312524488, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2 Hangzhou Kede Magnetic Components Co., Ltd. , Hangzhou 311500, China), AuthorCompanyExt(id=1291794370341884618, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, companyId=1291794370312524488, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2 杭州科德磁业有限公司 , 杭州 311500)])]), Author(id=1291794370878755555, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, orderNo=3, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1291794370941670118, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, authorId=1291794370878755555, language=EN, stringName=Baoguo ZHANG, firstName=Baoguo, middleName=null, lastName=ZHANG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=2, address=2 Hangzhou Kede Magnetic Components Co., Ltd. , Hangzhou 311500, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1291794370996196071, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, authorId=1291794370878755555, language=CN, stringName=张保国, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=2, address=2 杭州科德磁业有限公司 , 杭州 311500, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1291794370312524488, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, xref=2, ext=[AuthorCompanyExt(id=1291794370325107401, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, companyId=1291794370312524488, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2 Hangzhou Kede Magnetic Components Co., Ltd. , Hangzhou 311500, China), AuthorCompanyExt(id=1291794370341884618, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, companyId=1291794370312524488, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2 杭州科德磁业有限公司 , 杭州 311500)])]), Author(id=1291794371042333418, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, orderNo=4, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1291794371101053677, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, authorId=1291794371042333418, language=EN, stringName=Qifeng WEI, firstName=Qifeng, middleName=null, lastName=WEI, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=2, address=2 Hangzhou Kede Magnetic Components Co., Ltd. , Hangzhou 311500, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1291794371151385326, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, authorId=1291794371042333418, language=CN, stringName=魏启锋, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=2, address=2 杭州科德磁业有限公司 , 杭州 311500, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1291794370312524488, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, xref=2, ext=[AuthorCompanyExt(id=1291794370325107401, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, companyId=1291794370312524488, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2 Hangzhou Kede Magnetic Components Co., Ltd. , Hangzhou 311500, China), AuthorCompanyExt(id=1291794370341884618, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, companyId=1291794370312524488, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2 杭州科德磁业有限公司 , 杭州 311500)])]), Author(id=1291794371197522672, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, orderNo=5, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1291794371256242931, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, authorId=1291794371197522672, language=EN, stringName=Yuqing LI, firstName=Yuqing, middleName=null, lastName=LI, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1 College of Materials Science and Engineering, Beijing University of Technology , Beijing 100124, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1291794371302380280, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, authorId=1291794371197522672, language=CN, stringName=李玉卿, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1 北京工业大学 材料科学与工程学院 , 北京 100124, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1291794370228638402, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, xref=1, ext=[AuthorCompanyExt(id=1291794370245415620, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, companyId=1291794370228638402, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1 College of Materials Science and Engineering, Beijing University of Technology , Beijing 100124, China), AuthorCompanyExt(id=1291794370262192838, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, companyId=1291794370228638402, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1 北京工业大学 材料科学与工程学院 , 北京 100124)])]), Author(id=1291794371352711931, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, orderNo=6, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=yueming@bjut.edu.cn, emailSecond=null, emailThird=null, correspondingAuthor=1, authorType=1, ext={EN=AuthorExt(id=1291794371415626497, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, authorId=1291794371352711931, language=EN, stringName=Ming YUE, firstName=Ming, middleName=null, lastName=YUE, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1 College of Materials Science and Engineering, Beijing University of Technology , Beijing 100124, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1291794371461763844, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, authorId=1291794371352711931, language=CN, stringName=岳明, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1 北京工业大学 材料科学与工程学院 , 北京 100124, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1291794370228638402, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, xref=1, ext=[AuthorCompanyExt(id=1291794370245415620, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, companyId=1291794370228638402, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1 College of Materials Science and Engineering, Beijing University of Technology , Beijing 100124, China), AuthorCompanyExt(id=1291794370262192838, tenantId=1045748351789510663, journalId=1155139928303341754, articleId=1291789185343406291, companyId=1291794370228638402, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1 北京工业大学 材料科学与工程学院 , 北京 100124)])])]
陇赞,张东涛,张超越,张保国,魏启锋,李玉卿,岳明.
2∶17型SmCo基永磁材料的研究进展[J].
北京工业大学学报, 2026, 52(6): 662-680 DOI:10.11936/bjutxb2024080012
| [1] |
NESBITT E A, WERNICK J H, CORENZWIT E . Magnetic moments of alloys and compounds of iron and cobalt with rare earth metal additions[J]. Journal of Applied Physics, 1959, 30(3): 365-367.
|
| [2] |
HUBBARD W M, ADAMS E, GILFRICH J V . Magnetic moments of alloys of gadolinium with some of the transition elements[J]. Journal of Applied Physics, 1960, 31(5): S368-S369.
|
| [3] |
DAS D. Twenty million energy product samarium—cobalt magnet[J]. IEEE Transactions on Magnetics, 1969, 5(3): 214-216.
|
| [4] |
OJIMA T, TOMIZAWA S, YONEYAMA T, et al. New type rare earth cobalt magnets with an energy product of 30 MG·Oe[J]. Japanese Journal of Applied Physics, 1977, 16(4): 671-672.
|
| [5] |
SAGAWA M, FUJIMURA S, TOGAWA N, et al. New material for permanent magnets on a base of Nd and Fe (invited)[J]. Journal of Applied Physics, 1984, 55(6): 2083-2087.
|
| [6] |
CROAT J J, HERBST J F, LEE R W, et al. Pr—Fe and Nd—Fe—based materials: a new class of high—performance permanent magnets (invited)[J]. Journal of Applied Physics, 1984, 55(6): 2078-2082.
|
| [7] |
胡伯平, 饶晓雷, 王亦忠 . 稀土永磁材料: 上册[M]. 北京: 冶金工业出版社, 2017.
|
| [8] |
BUSCHOW K H J, VAN DER GOOT A S . Intermetallic compounds in the system samarium—cobalt[J]. Journal of the Less Common Metals, 1968, 14(3): 323-328.
|
| [9] |
STRNAT K J . Handbook of Ferromagnetic Materials[M]. Amsterdam: Elsevier, 1988: 131-209.
|
| [10] |
XU G, YANG J J, ZHANG D T, et al. Structure and magnetic properties of bulk nanocrystalline SmCo5 sintered magnet [J]. The Chinese Journal of Nonferrous Metals, 2009, 19(7): 1305-1309.
|
| [11] |
HORIUCHI Y, HAGIWARA M, ENDO M, et al. Influence of intermediate—heat treatment on the structure and magnetic properties of iron—rich Sm(CoFeCuZr)z sintered magnets [J]. Journal of Applied Physics, 2015, 117(17): 17C704.
|
| [12] |
陈虹宇, 马天宇, 宋欣, 等 . Sm2Co17磁体胞状组织边缘2∶17R′相的透射电子显微镜表征 [J]. 金属学报, 2021, 57(12): 1637.
|
| [13] |
CHEN H Y, MA T Y, SONG X, et al. Transmission electron microscopy characterization of the 2∶17R′ phase at the edge of cellular structure in Sm2Co17 magnets [J]. Acta Metallurgica Sinica, 2021, 57(12): 1637. (in Chinese)
|
| [14] |
朱明刚, 孙旭, 刘荣辉, 等 . 稀土功能材料2035发展战略研究[J]. 中国工程科学, 2020, 22(5): 1-158.
|
| [15] |
ZHU M G, SUN X, LIU R H, et al. Research on development strategy of rare earth functional materials 2035[J]. China Engineering Science, 2020, 22(5): 1-158. (in Chinese)
|
| [16] |
WU H C, LIU Z, ZHANG C Y, et al. Twinning, phase boundary structure and development of high coercivity in Fe—rich Sm2Co17—type magnets [J]. Journal of Rare Earths, 2022, 40(1): 102-111.
|
| [17] |
RABENBERG L, MISHRA R K, THOMAS G . Microstructures of precipitation—hardened SmCo permanent magnets[J]. Journal of Applied Physics, 1982, 53(3): 2389-2391.
|
| [18] |
HADJIPANAYIS G C, YADLOWSKY E J, WOLLINS S H . A study of magnetic hardening in Sm(Co0.69Fe0.22Cu0.07Zr0.02)7.22 [J]. Journal of Applied Physics, 1982, 53(3): 2386-2388.
|
| [19] |
WANG H, LI L, LIU B J, et al. Atomic—scale structure clarification of the planar Z phase and its influence on the magnetic properties in Sm(CoFeCuZr)z permanent magnets [J]. Acta Materialia, 2022, 230: 117846.
|
| [20] |
ZHANG Y, WU P F, LU Y, et al. Unveiling the anomalous atomic stacking and formation mechanism of 1∶3R Z—plates in Sm2Co17—type magnets [J]. Journal of Alloys and Compounds, 2023, 934: 167890.
|
| [21] |
FIDLER J . Coercivity of precipitation hardened cobalt rare earth 17∶2 permanent magnets[J]. Journal of Magnetism and Magnetic Materials, 1982, 30(1): 58-70.
|
| [22] |
GOPALAN R, HONO K, YAN A, et al. Direct evidence for Cu concentration variation and its correlation to coercivity in Sm(Co0.74Fe0.1Cu0.12Zr0.04)7.4 ribbons [J]. Scripta Materialia, 2009, 60(9): 764-767.
|
| [23] |
YAN A, HANDSTEIN A, GEMMING T, et al. Coercivity mechanism of Sm2(Co, Cu, Fe, Zr)17—based magnets prepared by melt—spinning [J]. Journal of Magnetism and Magnetic Materials, 2005, 290: 1206-1209.
|
| [24] |
MA B M, LIANG Y L, PATEL J, et al. The effect of Fe on the temperature dependent magnetic properties of Sm(Co, Fe, Cu, Zr)z and SmCo5 sintered magnets at 450 ℃ [J]. IEEE Transactions on Magnetics, 1996, 32(5): 4377-4379.
|
| [25] |
LIU S, RAY A E . Sm2(Co, Fe, Cu, Zr)17 magnets with higher Fe content [J]. IEEE Transactions on Magnetics, 1989, 25(5): 3785-3787.
|
| [26] |
DUERRSCHNABEL M, YI M, UESTUENER K, et al. Atomic structure and domain wall pinning in samarium—cobalt—based permanent magnets[J]. Nature Communications, 2017, 8: 54.
|
| [27] |
TANG W, ZHANG Y, HADJIPANAYIS G C . Microstructure and magnetic properties of Sm(CobalFexCu0.128Zr0.02)7.0 magnets with Fe substitution [J]. Journal of Magnetism and Magnetic Materials, 2000, 221(3): 268-272.
|
| [28] |
CHEN H S, WANG Y Q, YAO Y, et al. Attractive—domain—wall—pinning controlled Sm—Co magnets overcome the coercivity—remanence trade—off[J]. Acta Materialia, 2019, 164: 196-206.
|
| [29] |
YAN G H, LIU Z, XIA W X, et al. Grain boundary modification induced magnetization reversal process and giant coercivity enhancement in 2∶17 type SmCo magnets[J]. Journal of Alloys and Compounds, 2019, 785: 429-435.
|
| [30] |
MACHIDA H, FUJIWARA T, FUJIMOTO C, et al. Magnetic properties and microstructures of high heat—resistance Sm—Co magnets with high Fe and low Zr content[J]. AIP Advances, 2019, 9(12): 125042.
|
| [31] |
LI J, FANG M X, LIU Y, et al. Enhanced magnetic performance of Fe—rich Sm2Co17—type magnets by optimizing Zr content [J]. Journal of Materials Science & Technology, 2024, 193: 178-186.
|
| [32] |
SUN W, ZHU M G, FANG Y K, et al. Magnetic properties and microstructures of high—performance Sm2Co17 based alloy [J]. Journal of Magnetism and Magnetic Materials, 2015, 378: 214-216.
|
| [33] |
YANG J J, ZHANG D T, ZHANG H G, et al. Combination strategy for high—performance Sm(CoFeCuZr)z sintered permanent magnet: synergistic improvement of the preparation process [J]. Acta Materialia, 2023, 251: 118901.
|
| [34] |
HORIUCHI Y, HAGIWARA M, OKAMOTO K, et al. Effects of solution treated temperature on the structural and magnetic properties of iron—rich Sm(CoFeCuZr)z sintered magnet [J]. IEEE Transactions on Magnetics, 2013, 49(7): 3221-3224.
|
| [35] |
HORIUCHI Y, HAGIWARA M, OKAMOTO K, et al. Effect of pre—aging treatment on the microstructure and magnetic properties of Sm(Co, Fe, Cu, Zr)7.8 sintered magnets [J]. Materials Transactions, 2014, 55(3): 482-488.
|
| [36] |
SONG K K, FANG Y K, SUN W, et al. Microstructural analysis during the step—cooling annealing of iron—rich Sm(Co0.65Fe0.26Cu0.07Zr0.02)7.8 anisotropic sintered magnets [J]. IEEE Transactions on Magnetics, 2017, 53(11): 2100804.
|
| [37] |
ZHOU X L, YUAN T, MA T Y . Shortened processing duration of high—performance Sm—Co—Fe—Cu—Zr magnets by stress—aging[J]. Journal of Materials Science & Technology, 2022, 106: 70-76.
|
| [38] |
SONG X, JIA W T, LIU Y, et al. Rapid—thermal—process pre—treatment promoted precipitation towards strengthening hard magnetism of Sm2Co17—type magnets [J]. Acta Materialia, 2024, 274: 119966.
|
| [39] |
CAO J, ZHANG T L, LIU J H, et al. Grain boundary optimization induced substantial squareness enhancement and high performance in iron—rich Sm—Co—Fe—Cu—Zr magnets[J]. Journal of Materials Science & Technology, 2021, 85: 56-61.
|
| [40] |
RAY A E . Metallurgical behavior of Sm(Co, Fe, Cu, Zr)z alloys [J]. Journal of Applied Physics, 1984, 55(6): 2094-2096.
|
| [41] |
RAY A E . A revised model for the metallurgical behavior of 2∶17—type permanent magnet alloys[J]. Journal of Applied Physics, 1990, 67(9): 4972-4974.
|
| [42] |
XIONG X Y, OHKUBO T, KOYAMA T, et al. The microstructure of sintered Sm(Co0.72Fe0.20Cu0.055Zr0.025)7.5 permanent magnet studied by atom probe [J]. Acta Materialia, 2004, 52(3): 737-748.
|
| [43] |
GUTFLEISCH O, MÜLLER K H, KHLOPKOV K, et al. Evolution of magnetic domain structures and coercivity in high—performance SmCo 2∶17—type permanent magnets[J]. Acta Materialia, 2006, 54(4): 997-1008.
|
| [44] |
XUE Z Q, LIU L, LIU Z, et al. Mechanism of phase transformation in 2∶17 type SmCo magnets investigated by phase stabilization[J]. Scripta Materialia, 2016, 113: 226-230.
|
| [45] |
ZHU C Q, LIU Z, LUO H B, et al. Atomic—scale revelation of Cu diffusion mechanism in high—performance Pr—doped 2∶17—type SmCo magnets[J]. Acta Materialia, 2025, 282: 120492.
|
| [46] |
YAN A, GUTFLEISCH O, GEMMING T, et al. Microchemistry and magnetization reversal mechanism in melt—spun 2∶17—type Sm—Co magnets[J]. Applied Physics Letters, 2003, 83(11): 2208-2210.
|
| [47] |
WU H C, ZHANG C Y, LIU Z, et al. Nanoscale short—range ordering induced cellular structure and microchemistry evolution in Sm2Co17—type magnets [J]. Acta Materialia, 2020, 200: 883-892.
|
| [48] |
SONG X, MA T Y, ZHOU X L, et al. Atomic scale understanding of the defects process in concurrent recrystallization and precipitation of Sm—Co—Fe—Cu—Zr alloys[J]. Acta Materialia, 2021, 202: 290-301.
|
| [49] |
LIU L, PAN D L, LIU Z, et al. Optimization of magnetic properties of sintered (SmGdDy)(Co, Fe, Cu, Zr)z magnets by Dy—Co addition [J]. Journal of Magnetism and Magnetic Materials, 2015, 374: 634-638.
|
| [50] |
LIU L, LIU Z, LI M, et al. Positive temperature coefficient of coercivity in Sm1—xDyx(Co0.695Fe0.2Cu0.08Zr0.025)7.2 magnets with spin—reorientation—transition cell boundary phases [J]. Applied Physics Letters, 2015, 106(5): 052408.
|
| [51] |
LIU Z, LIU L, CHEN R J, et al. Optimization of temperature coefficient of remanence and magnetic properties of sintered Sm0.7Dy0.1Gd0.2(CobalFe0.2Cu0.08Zr0.025)7.2 magnets prepared by strip—casting technique [J]. IEEE Transactions on Magnetics, 2013, 49(12): 5599-5602.
|
| [52] |
DECROP B, DEPORTES J, DUFRESNE J, et al. Effects of different rare earths on the temperature dependence of rare earth cobalt magnets[J]. IEEE Transactions on Magnetics, 1981, 17(3): 1290-1293.
|
| [53] |
SKOMSKI R, COEY J M D . Permanent magnetism[M]. Boca Rato: CRC Press, 1999.
|
| [54] |
LI D, XU E D, LIU J, et al. The 2—17 type Sm2—xHRExCo10Cu1.5Fe3.2Zr0.2(HRE = Gd, Tb, Dy, Ho, Er) magnets with low temperature coefficient [J]. IEEE Transactions on Magnetics, 1980, 16(5): 988-990.
|
| [55] |
MILDRUM H F, KRUPAR J B, RAY A E . High coercive force 2—17 type Sm1—xErx(Co0.69Fe0.22Cu0.08Zr0.02)7.22 magnets with a low temperature coefficient [J]. Journal of the Less Common Metals, 1983, 93(2): 261-267.
|
| [56] |
JI C G, YANG J B, MAO W H, et al. High performance 2∶17 type SmCo permanent magnets with low temperature coefficients[J]. Solid State Communications, 1998, 108(9): 667-670.
|
| [57] |
CHEN C H, GONG W, WALMER M H, et al. Behavior of some heavy and light rare earth—cobalt magnets at high temperature[J]. Journal of Applied Physics, 2002, 91(10): 8483-8485.
|
| [58] |
LIU L, LIU Z, ZHANG X, et al. 2∶17 type SmCo magnets with low temperature coefficients of remanence and coercivity[J]. Journal of Magnetism and Magnetic Materials, 2019, 473: 376-380.
|
| [59] |
HUANG J Y, ZUO S L, ZHANG Q, et al. 2∶17—type SmCo permanent magnets with controllable remanence temperature coefficients via substitution of heavy rare earth elements[J]. Rare Metals, 2024, 43(8): 3990-3996.
|
| [60] |
ZHANG W Y, YAN A R, ZHANG H W, et al. Effect of the substitution of Gd for Sm on magnetic anisotropy of [J]. Journal of Physics D: Applied Physics, 2001, 34(7): 1065.
|
| [61] |
DAI H Y, HUANG J Y, ZUO S L, et al. Enhanced compensation effect of Gd and Dy in 2∶17—type SmCo magnets[J]. Scripta Materialia, 2025, 255: 116406.
|
| [62] |
RAY A, STRNAT K . Easy directions of magnetization in ternary R2(Co, Fe)17 phases [J]. IEEE Transactions on Magnetics, 1972, 8(3): 516-518.
|
| [63] |
LIU S Q . Sm—Co high—temperature permanent magnet materials[J]. Chinese Physics B, 2019, 28(1): 017501.
|
| [64] |
LIU J F, DING Y, ZHANG Y, et al. New rare—earth permanent magnets with an intrinsic coercivity of 10 kOe at 500 ℃[J]. Journal of Applied Physics, 1999, 85(8): 5660-5662.
|
| [65] |
LIU S, POTTS G, DOYLE G, et al. Effect of z value on high temperature performance of Sm(Co, Fe, Cu, Zr)z with z = 7.14 — 8.10 [J]. IEEE Transactions on Magnetics, 2000, 36(5): 3297-3299.
|
| [66] |
GUO Z H, PAN W, LI W . Sm(Co, Fe, Cu, Zr)z sintered magnets with a maximum operating temperature of 500 ℃ [J]. Journal of Magnetism and Magnetic Materials, 2006, 303(2): e396-e401.
|
| [67] |
YU N J, ZHU M G, FANG Y K, et al. The microstructure and magnetic characteristics of Sm(CobalFe0.1Cu0.09Zr0.03)7.24 high temperature permanent magnets [J]. Scripta Materialia, 2017, 132: 44-48.
|
| [68] |
YU N J, ZHU M G, SONG L W, et al. Coercivity temperature dependence of Sm2Co17—type sintered magnets with different cell and cell boundary microchemistry [J]. Journal of Magnetism and Magnetic Materials, 2018, 452: 272-277.
|
| [69] |
陇赞, 张超越, 凌冲, 等 . 低矫顽力温度系数Sm2Co17磁体的设计 [C]// 第十九届全国磁学和磁性材料会议. 北京: 中国材料研究学会, 2023: 147.
|
| [70] |
LONG Z, ZHANG C, LING C, et al. Design of low coercivity temperature coefficient Sm2Co17 magnets [C]// Proceedings of the 19th National Conference on Magnetism and Magnetic Materials. Beijing: Chinese Materials Research Society, 2023: 147. (in Chinese)
|
| [71] |
ZHANG T L, LIU H Y, LIU J H, et al. 2∶17—type SmCo quasi—single—crystal high temperature magnets[J]. Applied Physics Letters, 2015, 106(16): 162403.
|
| [72] |
XU H, WANG H, XI L L, et al. Influence of exchange coupling interaction on coercivity in 2∶17—type SmCo—based high temperature permanent magnets[J]. Scripta Materialia, 2023, 222: 115003.
|
| [73] |
FENG H B, CHEN H S, GUO Z H, et al. Investigation on microstructure and magnetic properties of Sm2Co17 magnets aged at high temperature [J]. Journal of Applied Physics, 2011, 109(7): 07A763.
|
| [74] |
LIU J F, HADJIPANAYIS G C . Demagnetization curves and coercivity mechanism in Sm(CoFeCuZr)z magnets [J]. Journal of Magnetism and Magnetic Materials, 1999, 195(3): 620-626.
|
| [75] |
TENG Y, LI Y Q, LIU W Q, et al. Coercivity mechanism of high—performance anisotropic heterostructure SmCo5 magnets [J]. Journal of Rare Earths, 2024, 42(10): 1882-1888.
|
| [76] |
FIDLER J, SKALICKY P . Microstructure of precipitation hardened cobalt rare earth permanent magnets[J]. Journal of Magnetism and Magnetic Materials, 1982, 27(2): 127-134.
|
| [77] |
DURST K D, KRONMÜLLER H, ERVENS W . Investigations of the magnetic properties and demagnetization processes of an extremely high coercive Sm(Co, Cu, Fe, Zr)7.6 permanent magnet: Ⅱ. The coercivity mechanism [J]. Physica Status Solidi (a), 1988, 108(2): 705-719.
|
| [78] |
LIVINGSTON J D, MARTIN D L . Microstructure of aged (Co, Cu, Fe)7Sm magnets [J]. Journal of Applied Physics, 1977, 48(3): 1350-1354.
|
| [79] |
NAGEL H. Coercivity and microstructure of Sm(Co0.87Cu0.13)7.8 [J]. Journal of Applied Physics, 1979, 50(2): 1026-1030.
|
| [80] |
KATTER M . Coercivity calculation of Sm2(Co, Fe, Cu, Zr)17 magnets [J]. Journal of Applied Physics, 1998, 83(11): 6721-6723.
|
| [81] |
LIU S, YANG J, DOYLE G, et al. New sintered high temperature Sm—Co based permanent magnet materials[J]. IEEE Transactions on Magnetics, 1999, 35(5): 3325-3327.
|
| [82] |
PANAGIOTOPOULOS I, GJOKA M, NIARCHOS D . Angular dependence of coercivity in Sm(Co, Fe, Cu, Zr)z magnets [J]. Journal of Magnetism and Magnetic Materials, 2004, 279(2/3): 389-395.
|
| [83] |
GABAY A M, TANG W, ZHANG Y, et al. Anomalous temperature dependence of coercivity and reversal mechanism in bulk—hardened rare earth—cobalt magnets[J]. Applied Physics Letters, 2001, 78(11): 1595-1597.
|
| [84] |
KRONMÜLLER H, GOLL D . Micromagnetic analysis of pinning—hardened nanostructured, nanocrystalline Sm2Co17 based alloys [J]. Scripta Materialia, 2002, 47(8): 545-550.
|
| [85] |
KRONMÜLLER H, GOLL D . Coercivity of 2∶17 based permanent magnets[J]. Journal of Iron and Steel Research, International, 2006, 13: 39-47.
|
| [86] |
GOLL D, KRONMÜLLER H, STADELMAIER H H . Micromagnetism and the microstructure of high—temperature permanent magnets[J]. Journal of Applied Physics, 2004, 96(11): 6534-6545.
|
| [87] |
KRONMÜLLER H, GOLL D . Analysis of the temperature dependence of the coercive field of Sm2Co17 based magnets [J]. Scripta Materialia, 2003, 48(7): 833-838.
|
| [88] |
CHUI S T . Towards a more analytic understanding of the pinning of domain walls in high—temperature permanent magnets[J]. Journal of Magnetism and Magnetic Materials, 2000, 217(1/2/3): 120-128.
|
基金资助
国家自然科学基金资助项目(51931007)
国家自然科学基金资助项目(51871005)
北京市教委科技发展项目(KZ202010005009)