钒基氧化物雷达与红外隐身材料研究进展

李昊宣 ,  刘朝辉 ,  程昱博

航空材料学报 ›› 2026, Vol. 46 ›› Issue (4) : 12 -28.

PDF (4828KB)
航空材料学报 ›› 2026, Vol. 46 ›› Issue (4) : 12 -28. DOI: 10.11868/j.issn.1005-5053.2025.000093
综述

钒基氧化物雷达与红外隐身材料研究进展

作者信息 +

Research progress on vanadium-based oxide radar and infrared stealth materials

Author information +
文章历史 +
PDF (4943K)

摘要

雷达与红外隐身材料对于提升装备隐身性能具有重要意义,近年来,钒基氧化物因其独特的热致相变特性、优异的红外辐射调制能力在雷达与红外隐身领域展现出广阔的应用前景。本文从多组分设计、结构调控、元素掺杂改性 3 个维度,系统阐述了二氧化钒(VO2)、三氧化二钒(V2O3)、五氧化二钒(V2O5)基隐身材料的性能优化方法及机制。此外,本文提出了钒基氧化物隐身材料研究未来的 5 大关键发展方向:(1)新型异质结构设计,通过结构调控设计克服钒基氧化物固有缺陷以增强隐身性能;(2)人工智能辅助材料设计,将利用机器学习建模成分-结构-性能关系,精准预测性能参数以缩短材料研发周期;(3)多元损耗机制协同优化,旨在耦合电导损耗、介电损耗与磁损耗实现协同增强,最大化提升隐身性能;(4)复杂界面表征,针对价态丰富导致的复杂界面,强化界面表征以揭示复合体系吸波机理;(5)宽频段自适应隐身,基于热致相变特性,开发兼具宽频段与自适应响应的隐身材料。

Abstract

Radar and infrared stealth materials play a crucial role in enhancing the stealth performance of equipment. In recent years,vanadium-based oxides have shown broad application prospects in the field of radar and infrared stealth due to their unique thermochromic phase transition properties and excellent infrared radiation modulation capabilities. This paper summarizes the research progress of vanadium-based oxide radar and infrared stealth materials at home and abroad. From three dimensions of multi-component design,structural regulation and element doping modification,it systematically elaborates on the performance optimization methods and mechanisms of vanadium dioxide,vanadium trioxide and vanadium pentoxide-based stealth materials. Furthermore,this paper proposes five key directions for future research on vanadium-based oxide stealth materials:(1) the design of new heterostructure,which aims to overcome the inherent defects of vanadium-based oxides through structural regulation to enhance stealth performance;(2) artificial intelligence-assisted material design,which will utilize machine learning to model the composition-structure-performance relationships and accurately predict performance parameters,thereby shortening the material development cycle;(3) the synergistic optimization of multiple loss mechanisms,intended to couple conductive loss,dielectric loss and magnetic loss for synergistic enhancement,maximizing the improvement of stealth performance;(4) the characterization of complex interfaces,which focuses on strengthening interface characterization to reveal the wave-absorbing mechanism of composite systems in view of the complex interfaces caused by rich valence states;(5) broadband adaptive stealth,which involves developing stealth materials with both broadband and adaptive response capabilities based on thermally induced phase transition characteristics.

关键词

钒基氧化物 / 红外隐身 / 雷达隐身 / 相变材料

Key words

vanadium-based oxide / infrared stealth / radar stealth / phase change material

引用本文

引用格式 ▾
李昊宣,刘朝辉,程昱博. 钒基氧化物雷达与红外隐身材料研究进展[J]. 航空材料学报, 2026, 46(4): 12-28 DOI:10.11868/j.issn.1005-5053.2025.000093

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1]

TAN X GU W H TAO Zet al. Carbon-based materials for radar-infrared compatible stealth technology[J].Chemical Engineering Journal2025507:160168.

[2]

JIN L ZHAO Y M CHEN Cet al. Application,development,and challenges of stealth materials/structures in next-generation aviation equipment[J].Applied Surface Science Advances202419:100575.

[3]

桑建华,周海. 飞行器表面电磁缺陷及雷达吸波材料应用[J].航空材料学报200323(2):51-55.

[4]

SANG J H ZHOU H . The electromagnetic discontinuities of the aircraft surface and an application of the radar absorbing materials[J].Journal of Aeronautical Materials200323(2):51-55.

[5]

孙敏,张雨. 隐身材料测试技术[M]. 北京:化学工业出版社,2014.

[6]

郭锦程,任素娥,陈彦飞. 高温红外隐身材料研究进展[J].材料工程202553(1):45-54.

[7]

GUO J C REN S E CHEN Y F . Research progress in high-temperature infrared stealth materials[J].Journal of Materials Engineering202553(1):45-54.

[8]

陈宇方,马国伟,周永江, . 智能雷达隐身材料研究现状[J].材料导报201125(23):40-44.

[9]

CHEN Y F MA G W ZHOU Y Jet al. Status of smart radar stealthy materials[J].Materials Review201125(23):40-44.

[10]

DEVTHADE V LEE S . Synthesis of vanadium dioxide thin films and nanostructures[J].Journal of Applied Physics2020128(23):231101.

[11]

SURNEV S RAMSEY M G NETZER F P . Vanadium oxide surface studies[J].Progress in Surface Science200373(4/5/6/7/8):117-165.

[12]

SZYMANSKI N J LIU Z T Y ALDERSON Tet al. Electronic and optical properties of vanadium oxides from first principles[J].Computational Materials Science2018146:310-318.

[13]

李尧,卢怡,曹文斌. W 掺杂二氧化钒的水热晶化机理及其相变性能[J].材料工程201745(11):58-65.

[14]

LI Y LU Y CAO W B . Crystallization mechanism and phase transition properties of W-doped VO2 synthesized by hydrothermal method[J].Journal of Materials Engineering201745(11):58-65.

[15]

DMITRIEV A V SHALAEVA E V VLADIMIROVA E Vet al. Stabilization of metallic phase in nanostructured hollow V2O3 spheres prepared by ultrasonic spray pyrolysis[J].Materials Research Bulletin2023167:112391.

[16]

VIJAYAKUMAR P SETHUPATHI N MAHALINGAM Pet al. Efficient electrochemical performance of V2O5/SrO nanocomposite electrode for supercapacitor application[J].Journal of Energy Storage2025119:116318.

[17]

刘顺华,刘军民,董星龙. 电磁波屏蔽及吸波材料[M]. 北京:化学工业出版社,2014.

[18]

张玉龙,李萍,石磊. 隐身材料[M]. 北京:化学工业出版社,2018.

[19]

彭智慧,曹茂盛,袁杰, . 雷达吸波材料设计理论与方法研究进展[J].航空材料学报200323(3):58-63.

[20]

PENG Z H CAO M S YUAN Jet al. Progress in design theory and methods research on radar absorbing materials[J].Journal of Aeronautical Materials200323(3):58-63.

[21]

陈旭生,李九生. 缺陷组合嵌入 VO2 薄膜结构的可调太赫兹吸收器[J].物理学报202069(2):233-239.

[22]

CHEN X S LI J S . Tunable terahertz absorber with multi-defect combination embedded VO2 thin film structure[J].Acta Physica Sinica202069(2):233-239.

[23]

LI M Y FANG C Q CHENG Y Let al. A facile pathway to fabricate VO2(M) nanoparticles via sol-gel method for flexible thermochromic films with efficient infrared stealth[J].Vacuum2024221:112885.

[24]

JI H N LIU D Q ZHANG C Yet al. VO2/ZnS core-shell nanoparticle for the adaptive infrared camouflage application with modified color and enhanced oxidation resistance[J].Solar Energy Materials and Solar Cells2018176:1-8.

[25]

LIANG S H GUAN H ZHANG H Net al. Intelligent off/on switchable electromagnetic wave absorbing material based on VO2 nanowires[J].Chemical Engineering Journal2024489:151025.

[26]

CHEN W X XING H L GAO S Tet al. Bi-semiconductor heterojunction Cu9S5@VO2 microspheres with morphology regulation as broadband high-performance electromagnetic wave absorber[J].Applied Surface Science2023610:155539.

[27]

BISWAS S . First-principles investigation of the metal-insulator transitions in Ti-substituted tetragonal rutile VO2 [J].Vacuum2023211:111922.

[28]

ZHANG Y Q XIONG W M CHEN W Jet al. Recent progress on vanadium dioxide nanostructures and devices:fabrication,properties,applications and perspectives[J].Nanomaterials202111(2):338.

[29]

GAO S T ZHANG Y C CHEN W Xet al. Heterojunction MoS2@VO2 microspheres for electromagnetic wave absorption in the X-band[J].ACS Applied Electronic Materials20235(11):6255-6265.

[30]

MA L SI H X FENG K Let al. Intelligent microwave absorption of VO2@PDA/RGO composites based on dynamic interfacial polarization performance[J].Journal of Applied Physics2024136(19):195102.

[31]

JI H N LIU D Q CHENG H Fet al. Hydrothermal synthesis and phase transition properties of uniform free-standing vanadium dioxide nanowires[J].Rare Metal Materials and Engineering201746(12):3601-3605.

[32]

付宇,王洋,蔡明. 气凝胶/纤维复合材料的热学和力学性能以及界面相容性的研究进展[J].材料工程202351(11):1-13.

[33]

FU Y WANG Y CAI M . Progress in thermal and mechanical properties and interfacial compatibility of aerogel/fiber composites[J].Journal of Materials Engineering202351(11):1-13.

[34]

WANG S N HAO X Q LIU Y Jet al. Intelligent tunable wave-absorbing CNTs/VO2/ANF composite aerogels based on temperature-driving[J].ACS Applied Materials & Interfaces202416(25):32773-32783.

[35]

CHENG Z WANG R F CAO Y Set al. Intelligent off/on switchable microwave absorption performance of reduced graphene oxide/VO2 composite aerogel[J].Advanced Functional Materials202232(40):2205160.

[36]

LIU J L ZHANG S Y QU Det al. Defects-rich heterostructures trigger strong polarization coupling in sulfides/carbon composites with robust electromagnetic wave absorption[J].Nano-Micro Letters202417(1):24.

[37]

LIU J L LIU Z L REN J Ket al. Selective ions exchange reactions endow defective heterovalent copper-based selenides with enhanced dielectric polarization response[J].Advanced Functional Materials202535(22):2420239.

[38]

LIU J L YIN M X LIU Z Let al. Solvent-engineered in-situ heterogenization of copper-based sulfides for broadening electromagnetic wave absorption[J].Chemical Engineering Journal2025507:160742.

[39]

MAO F Z LONG L ZENG G Let al. Achieving excellent electromagnetic wave absorption property by constructing VO2 coated biomass carbon heterostructures[J].Diamond and Related Materials2022130:109422.

[40]

CHEN Y MA Q S LI Xet al. Synthesis,characterization and electromagnetic absorbing performance of multi-step petaloid morphology VO2(M) [J].Ceramics International202046(16):25493-25502.

[41]

PAN F PEI K CHEN Get al. Integrated electromagnetic device with on-off heterointerface for intelligent switching between wave-absorption and wave-transmission[J].Advanced Functional Materials202333(49):2306599.

[42]

潘志浩. VO2/环氧树脂复合材料的设计制备及其智能调频吸波性能研究[D]. 开封:河南大学2024.

[43]

PAN Z H . Preparation of VO2/epoxy resin composites for intelligent frequency modulation microwave absorption[D]. Kaifeng:Henan University2024.

[44]

LIAO S Y WANG X Y SHI Y Yet al. Reversible switching between microwave absorption and EMI shielding of VO2 composite foam[J].Small2024:2402841.

[45]

CHEN X T GUO S N TAN S Jet al. An environmentally friendly chitosan-derived VO2/carbon aerogel for radar infrared compatible stealth[J].Carbon2023213:118313.

[46]

文娇,李介博,孙井永, . 红外探测与红外隐身材料研究进展[J].航空材料学报202141(3):66-82.

[47]

WEN J LI J B SUN J Yet al. Research progress of infrared detection and infrared stealth materials[J].Journal of Aeronautical Materials202141(3):66-82.

[48]

GAO Y YANG Q MA Let al. Radar-infrared compatible stealth technology in advanced nano-composite materials:mechanisms and structural optimization[J].Materials Today Nano202428:100534.

[49]

冯利利,刘一曼,姚琳, . 基于红外隐身及多波段兼容隐身材料[J].化学进展202133(6):1044-1058.

[50]

FENG L L LIU Y M YAO Let al. Infrared stealth and multi-band compatible stealth materials[J].Progress in Chemistry202133(6):1044-1058.

[51]

SILVEIRA F E M KURCBART S M . Hagen-Rubens relation beyond far-infrared region[J].Europhysics Letters201090(4):44004.

[52]

JI H N LIU D Q CHENG H Fet al. Vanadium dioxide nanopowders with tunable emissivity for adaptive infrared camouflage in both thermal atmospheric windows[J].Solar Energy Materials and Solar Cells2018175:96-101.

[53]

NIU J L WANG Y ZOU X Let al. Infrared electrochromic materials,devices and applications[J].Applied Materials Today202124:101073.

[54]

WU X Y YUAN L WENG X Let al. Passive smart thermal control coatings incorporating CaF2/VO2 core-shell microsphere structures[J].Nano Letters202121(9):3908-3914.

[55]

马创,王振,王新宇, . 红外可变发射率材料的研究[J].激光与红外202454(12):1871-1878.

[56]

MA C WANG Z WANG X Yet al. Study of infrared variable emissivity materials[J].Laser & Infrared202454(12):1871-1878.

[57]

LI B TIAN S Q WANG Zet al. Thermochromic Ta doped VO2 films:enhanced luminous transmittance,significantly depressed phase transition temperature and hysteresis width[J].Applied Surface Science2021568:150959.

[58]

ZHANG L M XIA F YAO J Net al. Facile synthesis,formation mechanism and thermochromic properties of W-doped VO2(M) nanoparticles for smart window applications[J].Journal of Materials Chemistry C20208(38):13396-13404.

[59]

KIM H J CHOI Y H LEE Det al. Enhanced passive thermal stealth properties of VO2 thin films via gradient W doping[J].Applied Surface Science2021561:150056.

[60]

WANG J ZENG L XIA M Xet al. Vanadium dioxide/aluminum composites for adaptive infrared stealth[J].Ceramics International202450(14):25034-25040.

[61]

LI M Y CHENG Y L FANG C Qet al. W/Al co-doping VO2 nanoparticles for high performance passive infrared stealth films with enhanced durability[J].Ceramics International202450(1):1443-1451.

[62]

CHEN F YUAN L WU X Yet al. Simultaneous tuning of the phase transition temperature and infrared optical properties of Mo-doped VO2 powders for intelligent infrared stealth materials[J].Ceramics International202349(15):25585-25593.

[63]

PHOEMPOON P SIKONG L . Synthesis of thermochromic Mo-doped VO2 particles[J].Materials Science Forum2016867:88-92.

[64]

JI H N LIU D Q CHENG H Fet al. Infrared thermochromic properties of monoclinic VO2 nanopowders using a malic acid-assisted hydrothermal method for adaptive camouflage[J].RSC Advances20177(9):5189-5194.

[65]

LI D L DENG S S ZHAO Z Jet al. VO2(M)@SnO2 core-shell nanoparticles:improved chemical stability and thermochromic property rendered by SnO2 shell[J].Applied Surface Science2022598:153741.

[66]

LI M Y FANG C Q CHENG Y Let al. Core-shell W-VO2@CeO2 nanoparticle with enhanced oxidation resistance for adaptive infrared stealth application[J].Ceramics International202551(10):13298-13308.

[67]

GAO J ZHANG H N HAN X Get al. The excellent infrared radiation regulation ability of VO2 nanorods[J].Solar Energy Materials and Solar Cells2024276:113082.

[68]

LI C C CHE P P XIE B Set al. Dual-phase change composites with temperature control and low infrared emissivity properties fabricated by electrospinning for infrared stealth and thermal camouflage[J].Science China Technological Sciences202467(12):3755-3765.

[69]

FANG K Y WANG Y J ZHAO Y Cet al. Infrared stealth nanofibrous composites with thermal adaptability and mechanical flexibility[J].Composites Science and Technology2021201:108483.

[70]

ZHANG X K LI N HU Z Met al. Direct fabrication of poly (p-phenylene terephthalamide) aerogel and its composites with great thermal insulation and infrared stealth[J].Chemical Engineering Journal2020388:124310.

[71]

程红飞,黄大庆. 多频谱兼容隐身材料研究进展[J].航空材料学报201434(5):93-99.

[72]

CHENG H F HUANG D Q . Research progress in multi-spectrum compatible stealth materials[J].Journal of Aeronautical Materials201434(5):93-99.

[73]

QAZILBASH M SCHAFGANS A BURCH Ket al. Electrodynamics of the vanadium oxides VO2 and V2O3 [J].Physical Review B200877(11):111-121.

[74]

JI H N LIU D Q CHENG H Fet al. Facile synthesis and electrical switching properties of V2O3 powders[J].Materials Science and Engineering:B2017217:1-6.

[75]

FU M ZHUANG Q R ZHU Z Tet al. Facile synthesis of V2O5/graphene composites as advanced electrode materials in supercapacitors[J].Journal of Alloys and Compounds2021862:158006.

[76]

DHOUNDIYAL H DAS P BHATNAGAR M C . Synthesis of V2O5 nanostructures and electrical transport properties of V2O5 nanoparticle[J].Materials Today:Proceedings202026:2830-2832.

[77]

CHENG S Y ZHANG C WANG Het al. Carbon nanofilm stabilized twisty V2O3 nanorods with enhanced multiple polarization behavior for electromagnetic wave absorption application[J].Journal of Materials Science & Technology2022119:37-44.

[78]

ZHAO J R WANG H LI Yet al. Construction of self-assembled bilayer core-shell V2O3 microspheres as absorber with superior microwave absorption performance[J].Journal of Colloid and Interface Science2023639:68-77.

[79]

NI A Q XIONG Z Q ZHANG Y Net al. Rail-like heterostructured porous carbon composites derived from vanadium metal-organic framework/butterfly wings for enhanced microwave absorption[J].Carbon2024221:118930.

[80]

ZHU Y T GUAN X M YANG Z Het al. Regulation of component transformation in MOF-derived vanadium oxide@C spindles for high-performance electromagnetic wave absorption[J].Journal of Alloys and Compounds2021865:158886.

[81]

ZHOU C H WU C LIU Det al. Metal-organic framework derived hierarchical Co/C@V2O3 hollow spheres as a thin,lightweight,and high-efficiency electromagnetic wave absorber[J].Chemistry-A European Journal201925(9):2234-2241.

[82]

LIANG C B HE J ZHANG Y Let al. MOF-derived CoNi@C-silver nanowires/cellulose nanofiber composite papers with excellent thermal management capability for outstanding electromagnetic interference shielding[J].Composites Science and Technology2022224:109445.

[83]

ZHOU J X JIA Z R ZHANG Yet al. Construction of 3D conductive network by flower-like V2O3 synergy with magnetic NiCo for superior electromagnetic wave absorption performance[J].Materials Today Physics202229:100902.

[84]

LIU T PANG Y ZHU Met al. Microporous Co@CoO nanoparticles with superior microwave absorption properties[J].Nanoscale20146(4):2447.

[85]

WU H J WU G L WU Q Fet al. Facile synthesis and microwave absorbability of C@Ni-NiO core-shell hybrid solid sphere and multi-shelled NiO hollow sphere[J].Materials Characterization201497:18-26.

[86]

ZHAO J R WANG H JIAO J Met al. Hierarchical waxberry-like V2O3@Co/Co3O4/Ni absorbers with remarkable microwave absorption via regulation of magnetic and dielectric loss[J].Applied Surface Science2024642:158582.

[87]

WANG Y J JIA W N PANG Z Bet al. High-performance electromagnetic wave absorption of nitrogen carbon doped composite materials with vanadium based nanowire structure at 2-18 GHz[J].Vacuum2024220:112826.

[88]

张圣斌,左敦稳,卢文壮, . 基于不同衬底的五氧化二钒薄膜光电特性[J].光学学报201636(4):321-328.

[89]

ZHANG S B ZUO D W LU W Zet al. Optical and electrical properties of vanadium pentoxide films deposited on different substrates[J].Acta Optica Sinica201636(4):321-328.

[90]

张圣斌,左敦稳,卢文壮, . 磁控溅射法制备的五氧化二钒薄膜光电特性[J].光学 精密工程201523(9):2438-2445.

[91]

ZHANG S B ZUO D W LU W Zet al. Optical and electrical properties of vanadium pentoxide films prepared by RF reactive magnetron sputtering[J].Optics and Precision Engineering201523(9):2438-2445.

[92]

LV H L YANG Z H PAN H Get al. Electromagnetic absorption materials:current progress and new frontiers[J].Progress in Materials Science2022127:100946.

[93]

ZHANG H XIE A J WANG C Pet al. Bifunctional reduced graphene oxide/V2O5 composite hydrogel:fabrication,high performance as electromagnetic wave absorbent and supercapacitor[J].ChemPhysChem201415(2):366-373.

[94]

CHEN J YE W P WANG Set al. Design of two-dimensional organic-inorganic heterostructures for high-performance electromagnetic wave absorption[J].Journal of Materials Chemistry C202311(32):10816-10827.

[95]

WANG W J RAN K HOU X Wet al. Interfacial modulation of organic-inorganic two-dimensional superlattices for efficient electromagnetic wave absorption[J].Chemical Engineering Journal2023451:138692.

[96]

YU J Q LI Y Q DUAN G Get al. Bio-templated fabrication of chain-spherical V2O5/C composites from dandelion fiber for high-efficiency electromagnetic wave absorption[J].Vacuum2022195:110683.

[97]

ZHEN Q LI L LI Ret al. Morphology controllable preparation and infrared emissivity of vanadium pentoxide[J].Infrared Physics & Technology201571:303-306.

[98]

HAO Z Y JIANG W K ZHU K Y . Carbon-encapsulated V2O3 nanorods for high-performance aqueous Zn-ion batteries[J].Frontiers in Chemistry202210:956610.

[99]

LIU C S YE X ZHOU B Yet al. 2D mesoporous nanomesh from N-doped carbon-encapsulated V2O3 nanowires as an anode for lithium-ion batteries[J].The Journal of Physical Chemistry C2020124(44):24073-24080.

[100]

SABNA M JAYARAM P SAFNA Ket al. Correlating structural and electronic properties with energy dissipation,polarization dynamics,and dielectric responses in V2O5-NiO-Sb2O3 micro-ceramics[J].Physica B:Condensed Matter2025704:417010.

AI Summary AI Mindmap
PDF (4828KB)

279

访问

0

被引

详细

导航
相关文章

AI思维导图

/