Kirkendall效应诱导空心结构材料在储能领域的应用

凌丹丹; 王琪; 张道洪; 王秋凡

doi:10.20056/j.cnki.ZNMDZK.XXXXXX01

中南民族大学学报（自然科学版） ›› 2025, Vol. 44 ›› Issue (06) : 721 -737. DOI: 10.20056/j.cnki.ZNMDZK.XXXXXX01

化学、材料与资源环境科学

Kirkendall效应诱导空心结构材料在储能领域的应用

凌丹丹 ¹ ,
王琪 ¹ ,
张道洪 ¹^,^a ,
王秋凡 ¹^,^a

作者信息 +

Kirkendall effect induced hollow structured materials for energy storage application

Dandan LING ¹ ,
Qi WANG ¹ ,
Daohong ZHANG ¹^,^a ,
Qiufan WANG ¹^,^a

Author information +

文章历史 +

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摘要

材料工程在电化学储能领域发挥着关键作用，近年来已经使用相当多的努力构建新型功能电极材料以满足电化学储能的未来要求.中空结构材料因其低密度、大比表面积和高孔隙率等而引起特别关注，使其成为能量转换和存储的潜在候选材料.Kirkendall效应已广泛应用于纳米空心结构的合成，该效应涉及通过反应界面的不平衡反向扩散.总结和讨论了利用纳米基尔肯达尔效应合成空心纳米结构的最新进展，包括一维（1-D）、二维（2-D）和三维（3-D）纳米颗粒及其在储能器件中的潜在应用，并对该研究领域的未来发展进行了展望.

Abstract

Materials engineering plays a key role in the field of electrochemical energy storage， and considerable efforts have been made in recent years to fulfill the future requirements of electrochemical energy storage using novel functional electrode materials. Materials with hollow structures are of particular interests due to their low density， large specific surface area and high porosity， making them promising candidates for energy conversion and storage. The Kirkendall effect has been widely applied for the synthesis of nanoscale hollow structures， which involves an unbalanced counter diffusion through a reaction interface. Herein， the recent progress on the use of the nanoscale Kirkendall effect to synthesize hollow nanostructures， including nanoparticles， one-dimensional （1-D）， two-dimensional （2-D）， and three-dimensional （3-D） nanostructures， and their potential applications in energy storage devices are summarized and discussed. And prospects is made for the future development of this research field.