PDF (974K)
摘要
硬质聚氨酯泡沫是一种优异的高分子材料,由于其具有比强度较高、冲击性能较好、力学性能优异等特性,被广泛应用于绝缘材料、隔热保温材料,建筑墙体保温材料及路面修补等。但是,硬质聚氨酯作为结构材料时需要承担一定的载荷,其绝对强度与结构材料相比较低,且力学性能较差,并不能满足某些特定领域的需要,需进行增强改性处理。目前,针对硬质聚氨酯增强改性研究取得了显著的进展,可通过化学改性、物理改性及结构设计等三种途径来提升硬质聚氨酯机械性能。本文基于改性机理,对国内外硬质聚氨酯泡沫增强改性研究现状及存在问题进行分析,且对硬质聚氨酯泡沫的发展前景进行展望。
Abstract
Rigid polyurethane foam is an excellent polymer material, known for its high specific strength, good impact performance, and superior mechanical properties. It is widely used in insulation materials, thermal insulation and heat preservation materials, building wall insulation, and road surface repairs. However, when used as a structural material, rigid polyurethane must bear certain loads. Its absolute strength and mechanical properties are relatively low compared to those of structural materials, which limits its application in certain specific fields. Therefore, it requires reinforcement and modification treatments. Significant progress has been made in the research on reinforcing and modifying rigid polyurethane foam, which can enhance its mechanical properties through chemical modification, physical modification, and structural design. This article analyzes the current status and existing issues of research on reinforcing and modifying rigid polyurethane foam both domestically and internationally, based on the mechanisms of modification, and also looks forward to the future development prospects of rigid polyurethane foam.
关键词
Key words
[Author(id=1278021711091212766, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1278021711158321634, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, authorId=1278021711091212766, language=EN, stringName=Xinyi Peng, firstName=Xinyi, middleName=null, lastName=Peng, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=Xinjiang Tianye (Group) Co., Ltd., Shihezi, Xinjiang, 832000, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1278021711212847588, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, authorId=1278021711091212766, language=CN, stringName=彭心怡, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=新疆天业(集团)有限公司, 中国·新疆 石河子 832000, bio={"content":"彭心怡(1996-),女,中国贵州人,硕士,工程师,从事化工机械研究。
"}, bioImg=null, bioContent=彭心怡(1996-),女,中国贵州人,硕士,工程师,从事化工机械研究。
, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1278021711003132377, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, xref=null, ext=[AuthorCompanyExt(id=1278021711024103898, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, companyId=1278021711003132377, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=Xinjiang Tianye (Group) Co., Ltd., Shihezi, Xinjiang, 832000, China), AuthorCompanyExt(id=1278021711040881115, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, companyId=1278021711003132377, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=新疆天业(集团)有限公司, 中国·新疆 石河子 832000)])]), Author(id=1278021711267373543, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, orderNo=1, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1278021711334482409, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, authorId=1278021711267373543, language=EN, stringName=Furong Shan, firstName=Furong, middleName=null, lastName=Shan, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=Xinjiang Tianye (Group) Co., Ltd., Shihezi, Xinjiang, 832000, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1278021711389008362, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, authorId=1278021711267373543, language=CN, stringName=单芙蓉, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=新疆天业(集团)有限公司, 中国·新疆 石河子 832000, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1278021711003132377, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, xref=null, ext=[AuthorCompanyExt(id=1278021711024103898, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, companyId=1278021711003132377, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=Xinjiang Tianye (Group) Co., Ltd., Shihezi, Xinjiang, 832000, China), AuthorCompanyExt(id=1278021711040881115, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, companyId=1278021711003132377, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=新疆天业(集团)有限公司, 中国·新疆 石河子 832000)])]), Author(id=1278021711435145709, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, orderNo=2, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1278021711498060272, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, authorId=1278021711435145709, language=EN, stringName=Li Li, firstName=Li, middleName=null, lastName=Li, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=Xinjiang Tianye (Group) Co., Ltd., Shihezi, Xinjiang, 832000, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1278021711540003313, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, authorId=1278021711435145709, language=CN, stringName=李丽, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=新疆天业(集团)有限公司, 中国·新疆 石河子 832000, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1278021711003132377, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, xref=null, ext=[AuthorCompanyExt(id=1278021711024103898, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, companyId=1278021711003132377, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=Xinjiang Tianye (Group) Co., Ltd., Shihezi, Xinjiang, 832000, China), AuthorCompanyExt(id=1278021711040881115, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, companyId=1278021711003132377, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=新疆天业(集团)有限公司, 中国·新疆 石河子 832000)])]), Author(id=1278021711586140659, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, orderNo=3, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1278021711695192565, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, authorId=1278021711586140659, language=EN, stringName=Zhonghua Zhao, firstName=Zhonghua, middleName=null, lastName=Zhao, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=Xinjiang Tianye (Group) Co., Ltd., Shihezi, Xinjiang, 832000, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1278021711741329911, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, authorId=1278021711586140659, language=CN, stringName=赵中华, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=新疆天业(集团)有限公司, 中国·新疆 石河子 832000, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1278021711003132377, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, xref=null, ext=[AuthorCompanyExt(id=1278021711024103898, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, companyId=1278021711003132377, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=Xinjiang Tianye (Group) Co., Ltd., Shihezi, Xinjiang, 832000, China), AuthorCompanyExt(id=1278021711040881115, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, companyId=1278021711003132377, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=新疆天业(集团)有限公司, 中国·新疆 石河子 832000)])]), Author(id=1278021711787467258, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, orderNo=4, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1278021711854576124, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, authorId=1278021711787467258, language=EN, stringName=Xingcai Ma, firstName=Xingcai, middleName=null, lastName=Ma, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=Xinjiang Tianye (Group) Co., Ltd., Shihezi, Xinjiang, 832000, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1278021711909102077, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, authorId=1278021711787467258, language=CN, stringName=马星才, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=新疆天业(集团)有限公司, 中国·新疆 石河子 832000, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1278021711003132377, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, xref=null, ext=[AuthorCompanyExt(id=1278021711024103898, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, companyId=1278021711003132377, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=Xinjiang Tianye (Group) Co., Ltd., Shihezi, Xinjiang, 832000, China), AuthorCompanyExt(id=1278021711040881115, tenantId=1045748351789510663, journalId=1253638279514964148, articleId=1278021710202020294, companyId=1278021711003132377, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=新疆天业(集团)有限公司, 中国·新疆 石河子 832000)])])]
彭心怡,单芙蓉,李丽,赵中华,马星才.
硬质聚氨酯泡沫增强改性的研究[J].
材料科学与应用技术, 2025, 4(2): 42-44 DOI:10.12349/msat.v4i2.5722
| [1] |
刘秀玉, 张冰, 韩祥祥, 等. 空心玻璃微珠/硬质聚氨酯泡沫复合材料的制备及性能[J]. 复合材料学报, 2020, 37(09):2094-2104
|
| [2] |
”Effect of crosslinking density on the mechanical properties of rigid polyuretha foams. ”Polymer Testing, 2021, 93: 106987
|
| [3] |
孙达, 李文风, 张雪萍, 等. 不同异氰酸酯指数和异氰酸酯复配对聚酯型聚氨酯泡沫的影响[J]. 合成材料老化与应用, 2021, 50(01):17-20.
|
| [4] |
刘娟, 李青芳, 韩悦, 等. 笼状硫代磷酸酯对聚氨酯泡沫性能的影响[J]. 塑料, 2017, 46(01):55-57+64.
|
| [5] |
陈金炎, 彭小波, 章林杰, 等. 邻甲苯二胺聚醚对硬质聚氨酯泡沫发泡工艺及性能的影响[J]. 聚氨酯工业, 2023, 38(05):40-42.
|
| [6] |
Li Y., et al. “Enhancement of mechanical properties of rigid polyurethane foams by incorporating aromatic polyester polyols.” Composites Part B: Engineering, 2020, 200:108348
|
| [7] |
耿皓. 纳米颗粒对包装材料硬质聚氨酯泡沫塑料力学性能的影响[J]. 包装工程, 2006,(04):50-52.
|
| [8] |
廉兆龙, 李晓屿, 陈鹏, 等. 碳纳米材料改性聚氨酯泡沫研究进展[J]. 科技导报, 2024, 42(09):85-93.
|
| [9] |
吕兵, 李冠杰. 不同粒径石墨增强硬质聚氨酯泡沫塑料的研究[J]. 北方建筑, 2018, 3(03):70-72.
|
| [10] |
巴志新, 戴玉明, 王章忠. 磨碎玻璃纤维增强硬质聚氨酯泡沫塑料的力学性能[J]. 材料开发与应用, 2005,(06):17-20.
|
| [11] |
余训章. 短切碳纤维增强硬质聚氨酯泡沫复合材料压缩强度与形貌研究[J]. 玻璃钢/复合材料, 2015,(02):28-31.
|
| [12] |
赵斌, 杨振国, 王建华, 等. 纤维与颗粒混杂增强聚氨酯硬泡塑料的制备及显微形貌[J]. 高分子材料科学与工程, 2005,(01):188-190+194.
|
| [13] |
许昆鹏. 碳纤维/纳米黏土增强聚氨酯泡沫塑料的研究[J]. 中国胶粘剂, 2017, 26(09):38-41.
|
| [14] |
刘钧, 鲍铮, 边佳燕. 空心玻璃微珠-氧化石墨烯协同增强聚氨酯泡沫的制备与压缩性能[J]. 材料导报, 2018, 32(S2):419-424.
|
基金资助
兵团重大科技项目-功能性聚氯乙烯基绿色建材关键技术研究与示范(2024AA006)