Pd/Py-COF催化喹啉加氢的性能研究

张永欣; 石中亮; 郭淼; 胡雁鸣

doi:10.13451/j.sxu.ns.2024099

山西大学学报(自然科学版) ›› 2025, Vol. 48 ›› Issue (03) : 596 -606. DOI: 10.13451/j.sxu.ns.2024099

化学

Pd/Py-COF催化喹啉加氢的性能研究

张永欣 ¹^,² ,
石中亮 ¹ ,
郭淼 ² ,
胡雁鸣 ²

作者信息 +

^1. 沈阳化工大学理学院辽宁省工业排放重金属处理与资源化技术工程研究中心，辽宁沈阳 110142

^2. 中国科学院大连化学物理研究所能源材料研究部，辽宁大连 116023

石中亮（SHI Zhongliang），E-mail：shzhl2000@163.com

郭淼（GUO Miao），E-mail：mguo@dicp.ac.cn

张永欣（1999 $-$ ），男，辽宁辽阳人，硕士研究生，研究方向为多相催化加氢。E-mail：yxzh@dicp.ac.cn

收起

The Promotion Effect of Pd/Py-COF in the Hydrogenation of Quinoline

Author information +

文章历史 +

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摘要

为了提升喹啉加氢制备1,2,3,4-四氢喹啉的反应活性，采用二维亚胺含芘共价有机骨架材料（Py-COF）为载体合成了Pd纳米颗粒催化剂（Pd/Py-COF），结果显示其在喹啉加氢中的活性是商用Pd/C催化剂的2.1倍。高分辨电镜、X射线光电子能谱、CO溶出伏安及对比实验等研究结果表明Pd/Py-COF的高活性来自富电子的Pd表面增加底物吸脱附及喹啉与Py-COF之间的弱相互作用。此外，Pd/Py-COF显示出了良好的循环使用性和底物适用性。该工作强调了采用COF骨架调控金属纳米粒子催化性能的重要性。

关键词

共价有机骨架材料 / 钯纳米颗粒 / 喹啉 / 加氢

Key words

covalent organic framework material / Pd nanoparticle / quinoline / hydrogenation

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